Saturday, June 1, 2024

Penn State Research Traced Radioactive Radium In Freshwater Mussels To Oil & Gas Wastewater

By Mariah Lucas,
Penn State News

Burrowed into streambeds and rarely moving for their decades-long lifespans, freshwater mussels are biomonitors, meaning they indicate how clean their environment is, according to Penn State researchers. 

As the bivalves feed on organic matter and filter the water around them, their inner tissues and hard shells begin to reflect whatever is in their environment — including radioactive particles. 

A pair of researchers from Penn State’s Department of Civil and Environment Engineering (CEE) analyzed the composition of mussels downstream of a centralized treatment facility in Western Pennsylvania that had accepted and treated fracking wastewater from the oil and gas industry for at least two decades. 

The now-decommissioned facility stopped accepting oil- and gas-produced wastewater in 2019.  

The researchers found that, even years later, the tissue and shells of mussels contained radium that could be traced to wastewater from fracking in the Marcellus Shale. 

The rock formation stretches underground from West Virginia through New York and is the largest natural gas field in the country. 

Their findings are available online now and will appear in the June issue of Science of the Total Environment.  

Though most facilities in Pennsylvania do not accept oil- and gas-produced water now, from 2008 to 2011, Pennsylvania’s rivers and streams saw a significant volume of treated wastewater that originated from fracking in the Marcellus Shale. 

Wastewater treatment facilities remove major contaminants, including radium, before discharging the water into surface water, like rivers, according to researchers. 

However, the treated water still contains trace amounts of contaminants and is five to 10 times saltier than ocean water.  

“With a much higher salinity than the surrounding environment, the discharged water has a different chemical fingerprint than what the mussels are used to,” said Nathaniel Warner, professor of CEE and corresponding author on the paper. “Mussels that were closest to the water discharges died off. Further downstream, the mussels found a way to tolerate the salinity and radioactive materials and instead absorbed them into their shells and tissues.”  

He explained that other types of wastewater generally do not contain many radioactive particles, but oil and gas wastewaters found deep in the earth and brought out by fracking often contain specific unique element ratios — a kind of signature that can be traced. 

The unique ratios of radioactive elements allowed the team to identify that the source of the contaminants is likely the treated Marcellus Shale wastewater. 

To collect the samples for radium analysis, Katharina Pankratz, a doctoral candidate in CEE and first author on the paper, contacted the Pennsylvania Department of Environmental Protection (DEP) to get a permit to sample mussels in the Allegheny River. 

DEP biologists, who offered to help with collection, identified the species that were present, then randomly collected 10 eastern spikes — a common type of mussel — from four designated locations along the river. 

The researchers found that half a kilometer downstream of a discharge site, mussels had approximately double the total radium levels as those upstream of the discharge site. And mussels five kilometers downstream of a discharge site had less than the mussels closer to the site, but still had a measurable amount of radium.  

Radiation exposure is measured in dose units known as micro-Seiverts (μSv). The researchers compared the radioactivity of the sampled eastern spikes to Brazil nuts, which take up radiation from the soil in which they grow. 

A 28-gram serving of Brazil nuts contain 0.47 to 0.80 μSv, while the maximum value calculated for a single mussel collected by researchers in the study was 63.42 μSv. 

The International Atomic Energy Agency recommends that individuals limit their annual exposure to no more than 1,000 μSv. Any more exposure can lead to health problems.  

“Along with nutrients, mussels also filter contaminants present in the water column, like metals, microplastics, synthetic chemical compounds and other emerging contaminants of concern,” Pankratz said. “Depending on the contaminant and its chemistry, if it is small enough to pass through the gills of the mussel, it has the potential to accumulate in their tissue or precipitate within the hard-shell structure.” 

While these mussels are not harvested for human consumption, larger species, like waterbirds, raccoons, muskrats and otters, regularly eat freshwater mussels, meaning the contamination could pass up the food chain, Pankratz said.   

“It raises concerns about potential impacts on other aquatic life, particularly endangered species more vulnerable to contaminants,” she said. “This information may help shape future regulations for wastewater disposal to surface water, especially in regions where mussels are harvested for food. I hope this study will inspire further research into the ecological consequences of these disposals worldwide.”  

The U.S. National Science Foundation supported this work.  


(Reprinted from Penn State News.)

Resource Links - Radioactive Oil & Gas Waste:

-- Penn State: Fracking Wastewater Accumulation Found In Freshwater Mussel Shells  [PaEN]

-- DEP: Potential For Environmental Impacts From Spills Or Leaks Of Radioactive Oil & Gas Waste Materials Is Real; Health Dept. Not Aware Of All Chemicals In Oil & Gas Wastewater Making Risk Assessment Difficult  [PaEN]

-- The Allegheny Front: New Book Takes On Radiation Dangers In Oil & Gas Industry   [PaEN]

-- Shale Gas & Public Health Conference: We've Got Enough Compelling Evidence To Enact Health Protective Policies For Families Now  [PaEN]

-- PA Oil & Gas Weekly Compliance Dashboard - June 24 to 30 - Radiation Levels Prompt Shale Gas Wastewater Tank Decontamination; Replugging Conventional, Shale Gas Wells  [PaEN]

-- DEP Reports Shale Gas Operations Sent Over 138,000 Cubic Feet Of Radioactive TENORM Waste To Low-Level Radioactive Waste Facilities For Disposal In 2022 - Over 911,000 Cubic Feet Since 2017   [PaEN]

-- Republican Rep. Krupa Introduces HB 1656 To Ban Oil, Gas Wastewater Injection Wells To Protect The Public From Radioactive, Toxic Materials  [PaEN]

-- DEP Issued Air Quality Permit For Leachate Evaporation System At Westmoreland Landfill With Special Radiation Monitoring Due To The Disposal Of Shale Gas Drilling Waste   [PaEN]

-- DEP Releases Final Guidance On Handling Radioactive Waste From Unconventional Shale Gas Drilling Operations   [PaEN]

-- Liberty Twp., Citizens Group Appeal EHB Decision On Permit For Tri-County Landfill In Mercer County Over Threats Posed By Birds, Radioactive Oil & Gas Waste   [PaEN]

-- EPA, West Virginia Officials Working To Secure Fairmount Oil & Gas Wastewater Processing Facility To Prevent Release Of Radioactive, Hazardous Materials   [PaEN]

-- Post-Gazette - Anya Litvak: Subsidiary Of PA Oil & Gas Waste Treatment Company Faces Mounting Pressure Over Radioactive Waste 

-- Earthworks: Rolling Stone Article Links Oil & Gas Waste Radioactivity To Worker Cancers, Wastewater Trucks Operating Illegally   [PaEN]

PA Oil & Gas Industry Public Notice Dashboards:

-- PA Oil & Gas Weekly Compliance Dashboard - May 25 to 31 - Shale Wastewater Pipeline Spill; Drill Cuttings Violations; More Abandoned Conventional Wells  [PaEN] 

-- PA Oil & Gas Industrial Facilities: Permit Notices, Opportunities To Comment - June 1 [PaEN] 

-- DEP Posted 62 Pages Of Permit-Related Notices In June 1 PA Bulletin  [PaEN] 

Related Articles This Week:

-- Week 10: Illegal Dumping Of Conventional Oil & Gas Wastewater Continues Unabated On Paved, Dirt Roads, Before It Rains, It Doesn’t Matter In Warren County  [PaEN]

-- The Derrick: PUC Judge Orders 7 Rhodes Estate Water Companies To Secure Counsel For Hearings On Their Future [More Fallout From Conventional Oil Well Wastewater Spill In Venango County]  [PaEN] 

-- Penn State Research Traced Radioactive Radium In Freshwater Mussels To Oil & Gas Wastewater  [PaEN] 

-- Protect PT Hosts 4 Virtual Workshops On How To Protect Yourself If You Live Near Shale Gas Facilities Starting June 11 [PaEN] 

-- Evangelical Environmental Network, Partners Host June 5 Webinar On Pipeline Methane Leaks - Causes, Impacts, Solutions  [PaEN]

-- Center For Coalfield Justice June 13 In-Person Program On Air Pollution Hazards From Oil & Gas Sites, South Franklin Township Park, Washington County

-- DEP Disapproves Final Cleanup Report On Dozens Of Chemicals At The American Refining Group Bradford Refinery In McKean County For Not Meeting Cleanup Standards [PaEN] 

-- Protect PT Lunch & Learn Online Program - Frac-Enomics, Is It Worth It? Now On Demand  [PaEN]  

-- Natural Resources Defense Council Releases Recommendations To US DOE On LNG Gas Export Facility Impact Analysis  [PaEN] 

-- DEP Extends Temporary Air Quality Permits For Shell Petrochemical Plant In Beaver County; Shell Said It Will Submit Full Title V Air Permit Application By June 21 Deadline  [PaEN]   

-- 50+ Appalachian Groups Call On US DOE To Suspend ARCH2 Hydrogen Hub Project  [PaEN]

NewsClips:

-- The Energy Age Blog: Cecil Twp., Washington County Latest Township To Realize Current Gas Well Regulations Aren’t Enough To Protect People 

-- Farm & Dairy: Cecil Twp., Washington County To Add New Restrictions On Oil & Gas Drilling - Like Living With A Helicopter 100 Feet Over Your Head 24 hours A Day

-- TribLive Guest Essay: Working To Plug More Dangerous Oil & Gas Wells Abandoned By Conventional Well Owners - By Rep. Mandy Steele (D-Allegheny)

-- Post-Gazette - Anya Litvak: Subsidiary Of PA Oil & Gas Waste Treatment Company Faces Mounting Pressure Over Radioactive Waste 

-- Inside Climate News: PA’s Fracking Wastewater Contains A ‘Shocking’ Amount Of The Critical Clean Energy Mineral Lithium 

--  WNEP: Coterra Energy Shale Gas Company Closing Facility In Susquehanna County, Laying Off 50+ Workers

-- PA Capital-Star/Capital & Main - Audrey Carleton: PA Gas Producers CNX Wants In On The Hydrogen Revolution

-- The Allegheny Front/WV Public Broadcasting: Mountain Valley Gas Pipeline Completion Delayed Again Due To Incomplete Pipeline Water Testing  

-- Delaware Currents: Gibbstown, NJ LNG Gas, Wyalusing LNG Gas Projects Show A Flicker Of Life

-- Reuters: EU Approves Law To Hit Gas Imports With Methane Emissions Limits To Cut Leaks In Gas Infrastructure 

[Posted: June 1, 2024]  PA Environment Digest

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